作者
Peter E Carlson, Alexandra L Noronha, Jay L Banner, John W Jenson, Mark W Moore, Judson W Partin, Michael Deininger, Daniel O Breecker, Kaylyn K Bautista
发表日期
2020/9/1
期刊
Geochimica et Cosmochimica Acta
卷号
284
页码范围
222-238
出版商
Pergamon
简介
Oxygen isotopes are the most commonly applied speleothem proxy for reconstructing Quaternary changes in precipitation and/or temperature. These interpretations are either limited to qualitative wetting and drying trends or rely on theoretical, experimental and/or empirical equilibrium isotope fractionation factors for more quantitative constraints. These various fractionation factors have similar temperature sensitivities, but their absolute values differ, and cave calcite does not appear to generally precipitate in isotopic equilibrium with its drip water. Rapid CO2 degassing paired with calcite precipitation, both occurring under disequilibrium conditions, are a set of mechanisms commonly invoked to explain offsets between observed and equilibrium isotopic fractionation between cave calcites and drip waters. However, the relevance of these disequilibrium mechanisms to speleothem records remains unresolved. Here …
引用总数
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