作者
SM Davachi, B Kaffashi, J Mohammadi Roushandeh
发表日期
2012/3
期刊
Polymers for Advanced Technologies
卷号
23
期号
3
页码范围
565-573
出版商
John Wiley & Sons, Ltd.
简介
The bioresorbable new terpolymers of L‐lactide, glycolide, and trimethylene carbonate were synthesized via ring‐opening polymerization reaction of the cyclic monomers using Stannous octoate as initiator. Glycolide and L‐lactide were prepared from their parent acids and then purified by multiple re‐crystallization from ethyl acetate. The thermal and mechanical properties of this polymer were characterized by means of thermogravimetry, differential scanning calorimetry, stress–strain measurements, and dynamic mechanical analysis. The glass transition temperature of the terpolymers changed from 33 to 51°C with composition in a predictable manner. The rheological properties of copolymers and molecular weight of each copolymer were determined showing good processability for making fibers. Using a mini‐extruder, it was possible to produce some filaments. The filaments produced at 140°C had appropriate …
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