作者
Douglas S Shephard, Thomas Maschmeyer, Brian FG Johnson, John Meurig Thomas, Gopinathan Sankar, Dogan Ozkaya, Wuzong Zhou, Richard D Oldroyd, Robert G Bell
发表日期
1997/11/3
期刊
Angewandte Chemie International Edition in English
卷号
36
期号
20
页码范围
2242-2245
出版商
Hüthig & Wepf Verlag
简介
A new hydrogenation catalyst is formed by thermolysis of the anionic carbonyl cluster [Ag 3 Ru 10 C 2 (CO) 28 Cl] 2− anchored to the mesoporous silicate MCM‐41. The cluster was isolated and characterized in MCM‐41 both before and after thermal treatment. The picture on the right shows a model, based in particular on EXAFS analysis, of the active bimetallic particle. The distribution of the Ag/Ru particles in the MCM‐41 cavities was determined by electron microscopy.
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DS Shephard, T Maschmeyer, BFG Johnson… - Angewandte Chemie International Edition in English, 1997