作者
Arnold J Boersma, Bas de Bruin, Ben L Feringa, Gerard Roelfes
发表日期
2012
期刊
Chemical communications
卷号
48
期号
18
页码范围
2394-2396
出版商
Royal Society of Chemistry
简介
DNA-based catalysis can be used to control the enantioselectivity of copper-catalysed Diels–Alder and Friedel–Crafts reactions to produce either enantiomer of the product by changing the denticity of the ligand coordinated to the Cu(II) ion, even though the DNA adopts a right handed helical conformation only.
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