作者
Ahmed IA Chowdhury, Jason I Gerhard, David Reynolds, Brent E Sleep, Denis M O'Carroll
发表日期
2017/4/15
期刊
Water research
卷号
113
页码范围
215-222
出版商
Pergamon
简介
Back diffusion of contaminants from low permeability strata has inhibited site remediation and closure due to an inability to deliver remediants into these strata. This study demonstrates the potential of electrokinetics (EK) to significantly reduce back diffusion of chlorinated compounds from low permeability porous media. Experiments were conducted in a two-dimensional sandbox packed with vertical layers of coarse sand and silt contaminated with aqueous trichloroethene (TCE). Three experiments, each approximately 41 days in duration, compared EK-enhanced in situ chemical oxidation (EK-ISCO) to EK or ISCO alone. EK-ISCO successfully delivered the oxidant (permanganate, PM) throughout the silt cross-section while ISCO without EK resulted only in PM delivery to the edges of the silt layer fringes. EK-ISCO resulted in a 4.4-fold reduction in TCE concentrations in the coarse sand compared to a 3.5-fold …
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