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Ethnic differences in the endowment with social capital can exacerbate intergroup inequalities. Pursuing this argument, we first compare the educational compositions of friendship networks between Turkish minority and native majority adolescents in Germany. Second, we pick up notions from Oppositional Culture Theory (OCT) to examine how ethnic differences in the composition of friendship networks come about. In a sample of 2,419 students in 74 secondary schools, we focus on the effort, achievement, and anti-school behaviour of peers and the role these play in adolescents’ friendship selection. Results from multilevel stochastic actor-oriented models reveal that Turkish minority adolescents prefer highly engaged and high-achieving peers as friends. Despite these preferences, Turkish minority adolescents’ social networks still provide lower levels of social capital on aggregate than majority members …