作者
Maharaja Jayapal, Ashanul Haque, Idris J Al-Busaidi, Rayya Al-Balushi, Mohammed K Al-Suti, Shahidul M Islam, Muhammad S Khan, Janke J Dittmer
发表日期
2017/8/1
期刊
Current Organic Chemistry
卷号
21
期号
19
出版商
Bentham Science Publishers
简介
Background
In the quest for sustainable energy materials, new donor and acceptor materials are being designed, synthesized and tested for photovoltaic (PV) applications. In this context, conjugated organic polymers have received significant interests in the last few decades.
Objective
In the present work, we synthesized an organic poly-yne P and assessed its efficiency as donor with a rylene acceptor EP-PTC.
Methods
The organic poly-yne P was synthesised via Sonogashira coupling and characterized by analytical and spectroscopic techniques. The PV performance of blends composed of different amounts of polymer P and acceptor EP-PTC was assessed. Computational studies were undertaken at DFT level to determine the geometry, dipole moment, Mulliken charge and energy level.
Results
A soluble blue low band-gap (1.72 eV) π-conjugated co-polymer consisting of dioctyloxyphenylene unit linked via …
学术搜索中的文章
M Jayapal, A Haque, IJ Al-Busaidi, R Al-Balushi… - Current Organic Chemistry, 2017