作者
Fatiha Mejbar, Youssef Miyah, Mohammed Benjelloun, Salma Ssouni, Khadija Saka, Anissa Lahrichi, Farid Zerrouq
发表日期
2024/6/1
期刊
Case Studies in Chemical and Environmental Engineering
卷号
9
页码范围
100572
出版商
Elsevier
简介
Catalytic reactivity performance is a significant challenge for catalytic wet peroxide oxidation (CWPO) technologies. Copper-impregnated eggshells (x%Cu@ES) were tested as a potential new low-cost catalyst to improve the CWPO process for the toxic dyes Congo Red (CR) and Crystal Violet (CV). The structure, morphology, and chemical composition of the x%Cu@ES catalyst were analyzed using FTIR, XRD, and SEM-EDX. Oxidative degradation of both dyes is enhanced by the presence of x%Cu@ES, which generates hydroxyl radicals in the reaction medium after contact with hydrogen peroxide. Decolorization rates according to the Box Behnken design are in the order of 99.88 % and 99.99 % for CR and CV respectively under the optimum conditions of 1 % copper content, 0.074 M H2O2 concentration, 60 mg L−1 dye concentration, and 2 g L−1 catalyst dose. After several regeneration cycles, the catalytic …
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