作者
Liliana P Silva, Eyad Qasem, Lakshmeesha Upadhyaya, Rebecca Esposito, Radosław Górecki, João AP Coutinho, Pedro J Carvalho, Suzana P Nunes
发表日期
2023/12/21
期刊
ACS Sustainable Chemistry & Engineering
卷号
12
期号
1
页码范围
300-309
出版商
American Chemical Society
简介
Membrane technology has been valuable for the transition to a fully sustainable economy. We demonstrate the application of amino-acid-based ionic liquids integrated into polymeric membranes for the preferential transport of carbon dioxide (CO2). This material has a high absorption capacity for CO2, increasing its solubility in the membrane and, consequently, permeability. The amino-acid-based ionic liquid is encapsulated in porous carbon capsules to avoid leaching out during the membrane operation. The selective layer polymer matrix was constituted by Pebax1657. The addition of 1 wt % of encapsulated amino-acid–base ionic liquid led to a more than 2-fold permeability enhancement while maintaining the ideal selectivity for CO2 over other light gases. The permeability was even higher when tested with humid mixed gases without compromising the selectivity.
引用总数
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