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In this study, combinations of ultrafine palm oil fuel ash (UPOFA) and ground blast furnace slag (GBFS) have been used to study the compressive strength and microstructure of the alkali-activated GBFS–UPOFA (AAGU) binary blended binder paste. GBFS (G) was added in varying percentages to alkaline activated UPOFA (AAU) such that the ratio of G/U + G varied from 0 to 0.3 at interval of 0.05. Sodium silicate (Na₂SiO₃) and sodium hydroxide (NaOH) with a final silicate modulus (Ms = SiO₂/Na₂O) of 1.58 were used as activators. Pozzolanic materials (G + U), activators, and free water were combined by weight ratios as: 1/0.35/0.02. A 28-day compressive strength of 44 MPa was achieved for G/U + G of 0.2 cured for 24 h at 60 °C. Finally, characterization was done using X-ray diffraction, SEM and FTIR and the analyses revealed that GBFS contributes significantly to the mechanical strength by pore filling effects …