作者
Leonard‐I Atanase, Gérard Riess
发表日期
2011/11
来源
Polymer international
卷号
60
期号
11
页码范围
1563-1573
出版商
John Wiley & Sons, Ltd.
简介
This review summarizes the background and recent advances of block copolymer stabilized oil‐in‐oil emulsions. For non‐polymerizable emulsions which have promising application possibilities for biomedical and cosmetic formulations, it is shown that tailor‐made block copolymers are by far the most efficient stabilizers with respect to low molecular weight surfactants. The characteristic features of oil‐in‐oil emulsions comprising one polymerizable phase are described. These types of non‐aqueous emulsions are of interest as nanoreactor systems for the polymerization of moisture‐sensitive monomers or catalysts. Furthermore they are the starting point of novel heterophase polymerization processes for the preparation of sterically stabilized polymer particles, as well as of ‘liquid‐filled polymeric materials’. The concept of oil‐in‐oil emulsions is finally extended to those systems where the two phases are …
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