作者
Sorin Marius Avramescu, Corina Bradu, Ion Udrea, Nicoleta Mihalache, Florin Ruta
发表日期
2008/8/30
期刊
Catalysis Communications
卷号
9
期号
14
页码范围
2386-2391
出版商
Elsevier
简介
The ozonation of oxalic acid has been carried out in an agitated slurry semi-batch reactor using NiO/Al2O3 as catalysts. The presence of catalysts in the ozonation processes significantly improves the oxalic acid removal rate, in comparison to the catalytic process. The influence of calcination temperature on the catalyst activity and on leaching of the active component was assessed. At the experimental conditions applied, the catalytic process develops under complete mineralization of organic substrate. The proposed mechanism justifies the first order kinetic experimental for oxalic acid and ozone. This kinetics also complies with experimental results obtained for different temperatures, ozone partial pressure and different mass of catalyst per slurry volume.
学术搜索中的文章
SM Avramescu, C Bradu, I Udrea, N Mihalache, F Ruta - Catalysis Communications, 2008