作者
Yuan Zhang, Heath Kersell, Roman Stefak, Jorge Echeverria, Violeta Iancu, UGE Perera, Yang Li, A Deshpande, K-F Braun, Christian Joachim, Gwenael Rapenne, S-W Hla
发表日期
2016/8
期刊
Nature nanotechnology
卷号
11
期号
8
页码范围
706-712
出版商
Nature Publishing Group UK
简介
A range of artificial molecular systems has been created that can exhibit controlled linear and rotational motion. In the further development of such systems, a key step is the addition of communication between molecules in a network. Here, we show that a two-dimensional array of dipolar molecular rotors can undergo simultaneous rotational switching when applying an electric field from the tip of a scanning tunnelling microscope. Several hundred rotors made from porphyrin-based double-decker complexes can be simultaneously rotated when in a hexagonal rotor network on a Cu(111) surface by applying biases above 1 V at 80 K. The phenomenon is observed only in a hexagonal rotor network due to the degeneracy of the ground-state dipole rotational energy barrier of the system. Defects are essential to increase electric torque on the rotor network and to stabilize the switched rotor domains. At low biases and …
引用总数
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