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The global defensive -alliance is a very well-studied notion in graph theory, it provides a method of classification of graphs based on relations between members of a particular set of vertices. In this paper, we explore this notion in zero-divisor graph of commutative rings. The established results generalize and improve recent work by Muthana and Mamouni who treated a particular case for known by the global defensive alliance. Various examples are also provided which illustrate and delimit the scope of the established results.