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Polystyrene is widely used in formulations intended for children use. The main problem with this plastic is the residual styrene, which can migrate from the product, and therefore, be in contact with children. The acute toxicity of styrene is well known, raising the need of an efficient and fast method of analysis for this compound. Several extraction methods have been evaluated and compared for the determination of residual styrene monomer in polystyrene granules used in toys: supercritical fluid extraction (SFE), microwave-assisted extraction (MAE), Soxhlet extraction, headspace emission and dissolution–precipitation. The analyte was subsequently detected by gas chromatography (GC) with MS detection. The results indicated that the most efficient method was dissolution–precipitation giving even higher extraction efficiency than SFE. For validating the method, PS samples spiked with known quantities of styrene at …