作者
Jianyin Xiong, Zhangcan He, Xiaochen Tang, Pawel K Misztal, Allen H Goldstein
发表日期
2019/6/19
期刊
Environmental science & technology
卷号
53
期号
14
页码范围
8262-8270
出版商
American Chemical Society
简介
Volatile organic chemicals are produced from reactions of ozone with squalene in human skin oil. Both primary and secondary reaction products, i.e., 6-methyl-5-hepten-2-one (6-MHO) and 4-oxopentanal (4-OPA), have been reported in indoor occupied spaces. However, the abundance of these products indoors is a function of many variables, including the amount of ozone and occupants present as well as indoor removal processes. In this study, we develop a time-dependent kinetic model describing the behavior of ozone/squalene reaction products indoors, including the reaction process and physical adsorption process of products on indoor surfaces. The key parameters in the model were obtained by fitting time-resolved concentrations of 6-MHO, 4-OPA, and ozone in a university classroom on 1 day with multiple class sessions. The model predictions were subsequently tested against observations from four …
引用总数
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