作者
Hadi Mehrabian, Jacco H Snoeijer, Jens Harting
发表日期
2017/3
期刊
APS March Meeting Abstracts
卷号
2017
页码范围
G1. 361
简介
Efficiency of soft particles to stabilize emulsions is examined by measuring their desorption energy ie the energy required to detach the particle form a fluid interface. Microgels as well as generic deformable particles are considered. Soft particles and the interface are modeled using molecular dynamics simulations and the free-energy is calculated using the thermodynamic integration method. It is shown that the softness affects the particle-interface binding in two opposing directions. On the one hand, a soft particle spreads at the interface, removes a larger liquid-liquid contact area, and thus is energetically more favorable than a rigid particle. On the other hand, softness gives the particle an extra degree of freedom to get reshaped instead of deforming the interface, producing a smaller excess interfacial area during the detachment, and hence faces a smaller energy barrier to detach. Eventually, the first effect …
学术搜索中的文章
H Mehrabian, JH Snoeijer, J Harting - APS March Meeting Abstracts, 2017