作者
Hadi Mehrabian, Jacco H Snoeijer, Jens Harting
发表日期
2020
期刊
Soft matter
卷号
16
期号
37
页码范围
8655-8666
出版商
Royal Society of Chemistry
简介
The efficiency of soft particles to stabilize emulsions is examined by measuring their desorption free energy, i.e., the mechanical work required to detach the particle from a fluid interface. Here, we consider rubber-like elastic as well as microgel particles, using coarse-grained molecular dynamics simulations. The energy of desorption is computed for two and three-dimensional configurations by means of the mean thermodynamic integration method. It is shown that the softness affects the particle–interface binding in two opposing directions as compared to rigid particles. On the one hand, a soft particle spreads at the interface and thereby removes a larger unfavorable liquid–liquid contact area compared to rigid particles. On the other hand, softness provides the particle with an additional degree of freedom to get reshaped instead of deforming the interface, resulting in a smaller restoring force during the detachment …
引用总数
20212022202320243732
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