作者
Alexander H Ip, Susanna M Thon, Sjoerd Hoogland, Oleksandr Voznyy, David Zhitomirsky, Ratan Debnath, Larissa Levina, Lisa R Rollny, Graham H Carey, Armin Fischer, Kyle W Kemp, Illan J Kramer, Zhijun Ning, André J Labelle, Kang Wei Chou, Aram Amassian, Edward H Sargent
发表日期
2012/9
期刊
Nature nanotechnology
卷号
7
期号
9
页码范围
577-582
出版商
Nature Publishing Group UK
简介
Colloidal quantum dot (CQD) films allow large-area solution processing and bandgap tuning through the quantum size effect,,,,,. However, the high ratio of surface area to volume makes CQD films prone to high trap state densities if surfaces are imperfectly passivated, promoting recombination of charge carriers that is detrimental to device performance. Recent advances have replaced the long insulating ligands that enable colloidal stability following synthesis with shorter organic linkers or halide anions,,,,, leading to improved passivation and higher packing densities. Although this substitution has been performed using solid-state ligand exchange, a solution-based approach is preferable because it enables increased control over the balance of charges on the surface of the quantum dot, which is essential for eliminating midgap trap states,. Furthermore, the solution-based approach leverages recent progress in …
引用总数
20122013201420152016201720182019202020212022202315148203186157153130110104966261
学术搜索中的文章
AH Ip, SM Thon, S Hoogland, O Voznyy, D Zhitomirsky… - Nature nanotechnology, 2012