作者
Giulio Ragazzon, Massimo Baroncini, Serena Silvi, Margherita Venturi, Alberto Credi
发表日期
2015/1
期刊
Nature nanotechnology
卷号
10
期号
1
页码范围
70-75
出版商
Nature Publishing Group UK
简介
Biomolecular motors convert energy into directed motion and operate away from thermal equilibrium. The development of dynamic chemical systems that exploit dissipative (non-equilibrium) processes is a challenge in supramolecular chemistry and a premise for the realization of artificial nanoscale motors. Here, we report the relative unidirectional transit of a non-symmetric molecular axle through a macrocycle powered solely by light. The molecular machine rectifies Brownian fluctuations by energy and information ratchet mechanisms and can repeat its working cycle under photostationary conditions. The system epitomizes the conceptual and practical elements forming the basis of autonomous light-powered directed motion with a minimalist molecular design.
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