作者
Christoph Humborg, Marc C Geibel, Xiaole Sun, Michelle McCrackin, Carl-Magnus Mörth, Christian Stranne, Martin Jakobsson, Bo Gustafsson, Alexander Sokolov, Alf Norkko, Joanna Norkko
发表日期
2019/8/7
期刊
Frontiers in Marine Science
卷号
6
页码范围
493
出版商
Frontiers Media SA
简介
The summer heat wave in 2018 led to the highest recorded water temperatures since 1926 – up to 21°C – in bottom coastal waters of the Baltic Sea, with implications for the respiration patterns in these shallow coastal systems. We applied cavity ring-down spectrometer measurements to continuously monitor carbon dioxide (CO2) and methane (CH4) surface-water concentrations, covering the coastal archipelagos of Sweden and Finland and the open and deeper parts of the Northern Baltic Proper. This allowed us to (i) follow an upwelling event near the Swedish coast leading to elevated CO2 and moderate CH4 outgassing, and (ii) to estimate CH4 sources and fluxes along the coast by investigating water column inventories and air-sea fluxes during a storm and an associated downwelling event. At the end of the heat wave, before the storm event, we found elevated CO2 (1583 μatm) and CH4 (70 nmol/L) concentrations. During the storm, a massive CO2 sea-air flux of up to 274 mmol m–2 d–1 was observed. While water-column CO2 concentrations were depleted during several hours of the storm, CH4 concentrations remained elevated. Overall, we found a positive relationship between CO2 and CH4 wind-driven sea-air fluxes, however, the highest CH4 fluxes were observed at low winds whereas highest CO2 fluxes were during peak winds, suggesting different sources and processes controlling their fluxes besides wind. We applied a box-model approach to estimate the CH4 supply needed to sustain these elevated CH4 concentrations and the results suggest a large source flux of CH4 to the water column of 2.5 mmol m–2 d–1. These results …
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