作者
Kevin Ingersent, Jacob Klein, Philip Pincus
发表日期
1986/9
期刊
Macromolecules
卷号
19
期号
5
页码范围
1374-1381
出版商
American Chemical Society
简介
Analytical expressions, based on a mean-field model and derived in a previous paper (part 1: Klein, J.; Pincus, PA Macromolecules 1982, 15, 1129), for the interaction between two parallel plates bearing adsorbed polymer in poor-solvent medium, are solved numerically to yield (a) segmental density profiles of the adsorbed polymer and (b) interaction-energy vs. plate-separation profiles. All parameters appearing in these calculations are obtainable from bulk data such as the polymer-solvent phase diagram and adsorbance measurements. The calculated results are critically compared with model experiments on forces between smooth mica surfaces bearing polystyrene in cyclohexane in poor-solvent conditions: the agreement is qualitatively very good and quantitatively fair. Some improvements to the model are suggested.
引用总数
学术搜索中的文章
K Ingersent, J Klein, P Pincus - Macromolecules, 1986