作者
Rajeev S Menon, Akkattu T Biju, Vijay Nair
发表日期
2015
来源
Chemical Society Reviews
卷号
44
期号
15
页码范围
5040-5052
出版商
Royal Society of Chemistry
简介
The use of NHCs for generating homoenolate species has gained widespread popularity in recent years. A number of highly stereoselective processes of NHC-homoenolates have emerged. Homoenolate reactions have also been employed as key steps in the total synthesis of a number of natural products. The use of compatible co-catalysts, improved NHC-catalyst design and the use of novel precursors for homoenolate generation are among the major developments in this area that were disclosed recently. This tutorial review organises and presents the advancements in this rapidly growing area of catalysis and in the process updates a previous account published in 2011 in this journal.
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