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Increase in transmission symbol-rate as well as order of quadrature amplitude modulation (QAM) is identified as the most economical way to reduce cost per transmitted bit. In particular, next generation transponders aim at supporting data-rates up to 1 Tb/s employing superchannels due to electrical components' bandwidth limitations. Furthermore, the introduction of a flexible-grid architecture can maximize throughput by minimizing spectral gaps in available optical spectrum. Keeping in view these design options, we conducted several high capacity experiments with tier1 operator Orange using their field deployed standard single mode fiber (SSMF, G.652), having a total length of 762 km, connecting the cities Lyon and Marseille in France. In particular we employed four subcarriers per Tb/s superchannel, each modulated by PM-16QAM, PM-32QAM, and PM-64QAM with per carrier symbol-rates of 41.2 GBd, 33 …