作者
Junhua Luo, Yusheng Zhao, Hongwu Xu, Tiffany L Kinnibrugh, Dali Yang, Tatiana V Timofeeva, Luke L Daemen, Jianzhong Zhang, Wei Bao, Joe D Thompson, Robert P Currier
发表日期
2007/10/29
期刊
Inorganic chemistry
卷号
46
期号
22
页码范围
9021-9023
出版商
American Chemical Society
简介
A novel cobalt(II)−organic framework, [Co2(OH)(3,4-PBC)3]n (I), has been acquired by the reaction of CoO with an unsymmetrical pyridylbenzoate ligand, 3-pyrid-4-ylbenzoic acid (3,4-PBC). Single-crystal X-ray diffraction studies reveal that it is comprised of [CoII4(μ3-OH)2] clusters linked by the unsymmetrical ligand 3,4-PBC, forming a novel helical double-layered metal−organic architecture. A significant overall antiferromagnetic behavior has been observed for this compound.
学术搜索中的文章
J Luo, Y Zhao, H Xu, TL Kinnibrugh, D Yang… - Inorganic chemistry, 2007