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We studied optical properties and photocurrent characteristics of PbS nanowires grown by chemical vapor deposition. Distinct bandedge photoluminescence (PL) emission was observed in the mid-infrared spectral range and the quantum confinement effect estimated from the PL peak energy was within 40 meV, consistent with the average diameter of the nanowire (∼ 70 nm) being significantly larger than the exciton Bohr radius (∼ 18 nm). We also demonstrated interdigit photo detectors making use of these PbS nanowires suspended between two pre-patterned Ti electrodes, where Ti also acted as metal catalyst for the nanowire growth. The threshold wavelength of the photocurrent was found to be∼ 3 μm at room temperature.