作者
Dandan Zhang, Yiming Yang, Yehonadav Bekenstein, Yi Yu, Natalie A Gibson, Andrew B Wong, Samuel W Eaton, Nikolay Kornienko, Qiao Kong, Minliang Lai, A Paul Alivisatos, Stephen R Leone, Peidong Yang
发表日期
2016/6/6
期刊
Journal of the American Chemical Society
卷号
138
期号
23
页码范围
7236-7239
出版商
American Chemical Society
简介
Here, we demonstrate the successful synthesis of brightly emitting colloidal cesium lead halide (CsPbX3, X = Cl, Br, I) nanowires (NWs) with uniform diameters and tunable compositions. By using highly monodisperse CsPbBr3 NWs as templates, the NW composition can be independently controlled through anion-exchange reactions. CsPbX3 alloy NWs with a wide range of alloy compositions can be achieved with well-preserved morphology and crystal structure. The NWs are highly luminescent with photoluminescence quantum yields (PLQY) ranging from 20% to 80%. The bright photoluminescence can be tuned over nearly the entire visible spectrum. The high PLQYs together with charge transport measurements exemplify the efficient alloying of the anionic sublattice in a one-dimensional CsPbX3 system. The wires increased functionality in the form of fast photoresponse rates and the low defect density suggest …
引用总数
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