作者
Anshul DS Parmar, Srikanth Sastry
发表日期
2015/7/15
期刊
The Journal of Physical Chemistry B
卷号
119
期号
34
页码范围
11243-11252
出版商
American Chemical Society
简介
An understanding of the origin of fragility, which the rapidity of change of viscosity and related dynamical quantities, has been sought by a variety of approaches over the years. Within the framework of the Adam–Gibbs relation, fragility is in principle related to both the temperature variation of configurational entropy and the high temperature activation energy. Many theoretical analyses have been focused on the variation of configuration entropy, although the importance of the high temperature activation energy in determining the fragility of a glass former has also been emphasized. We explore the latter aspect by considering a model liquid whose high temperature activation energy is modified by hand, through the introduction of a tunable barrier to bond breaking. We show that changes in such a barrier are able to modify the fragility measured from the temperature dependence of dynamical quantities, while a …
引用总数
20162017201820192020202120224241222