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Blue phase liquid crystals (BPLC) are known to be useful for various non-trivial applications due to their nanoscale self-assembled cubic crystalline structures. Even though the BPLC exhibits an efficient optically isotropic phase due to the double helical confinement of liquid crystal (LC) molecules within a few hundred-nanometer range, this hinders the orientation of LC molecules along the applied field direction. Consequently, the BPLC demands larger driving fields to operate, degrading the device’s performance in real-world applications. In this context, we provide a chiral monomer template for BPLC that decreases the driving field by 52 % while the electro-optical responses remain unaffected. Furthermore, our approach provides higher thermal stability, with a broader BPLC phase range (42 °C), including near ambient temperature. As this approach potentially overcomes the fundamental challenges of BPLC …