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The development of e-business models is becoming increasingly popular within both the academic and business arenas, and decision maker have been facing an enormous range of e-business models from which they are going to choose one. The role of knowledge in new economy is so deterministic and e-business, as a highly knowledge-based area, requires more attention. We propose and provide a decision support framework for evaluating knowledge inventory, which includes: human capital, relational capital and structural capital, to select e-business models. Our model is a useful tool for managers in making better strategic plan within their organizations, in order to exclude those e-business models which are not applicable regarding knowledge capabilities.