作者
Yi Tian, Francisco Pelayo García de Arquer, Cao‐Thang Dinh, Gael Favraud, Marcella Bonifazi, Jun Li, Min Liu, Xixiang Zhang, Xueli Zheng, Md Golam Kibria, Sjoerd Hoogland, David Sinton, Edward H Sargent, Andrea Fratalocchi
发表日期
2017/7
期刊
Advanced Materials
卷号
29
期号
27
页码范围
1701165
简介
The direct conversion of solar energy into fuels or feedstock is an attractive approach to address increasing demand of renewable energy sources. Photocatalytic systems relying on the direct photoexcitation of metals have been explored to this end, a strategy that exploits the decay of plasmonic resonances into hot carriers. An efficient hot carrier generation and collection requires, ideally, their generation to be enclosed within few tens of nanometers at the metal interface, but it is challenging to achieve this across the broadband solar spectrum. Here the authors demonstrate a new photocatalyst for hydrogen evolution based on metal epsilon‐near‐zero metamaterials. The authors have designed these to achieve broadband strong light confinement at the metal interface across the entire solar spectrum. Using electron energy loss spectroscopy, the authors prove that hot carriers are generated in a broadband fashion …
引用总数
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