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Remote sensing of urban heat islands (UHIs) has traditionally used the Normalized Difference Vegetation Index (NDVI) as the indicator of vegetation abundance to estimate the land surface temperature (LST)–vegetation relationship. This study investigates the applicability of vegetation fraction derived from a spectral mixture model as an alternative indicator of vegetation abundance. This is based on examination of a Landsat Enhanced Thematic Mapper Plus (ETM+) image of Indianapolis City, IN, USA, acquired on June 22, 2002. The transformed ETM+ image was unmixed into three fraction images (green vegetation, dry soil, and shade) with a constrained least-square solution. These fraction images were then used for land cover classification based on a hybrid classification procedure that combined maximum likelihood and decision tree algorithms. Results demonstrate that LST possessed a slightly stronger …