作者
Tomoko Shirahase, Yoichi Komatsu, Hironori Marubayashi, Yoichi Tominaga, Shigeo Asai, Masao Sumita
发表日期
2007/8/1
期刊
Polymer degradation and stability
卷号
92
期号
8
页码范围
1626-1631
出版商
Elsevier
简介
Poly(l-lactide) (PLLA) was melt-blended with poly(p-vinyl phenol) (PVPh) using a two-roll mill, and the miscibility between PLLA and PVPh and degradation of the blend films were investigated. It was found that PLLA/PVPh blend has miscibility in the amorphous state because only single Tg was observed in the DSC and DMA measurements. The Tg of the PLLA/PVPh blend could be controlled in the temperature range from 55°C to 117°C by changing the PVPh weight fraction. In alkaline solution, degradation rate of PLLA/PVPh blends was faster than that of neat PLLA because PVPh could dissolve in alkaline solution. The surface morphology of degraded PLLA and PLLA/PVPh blend were observed by SEM. The surface morphology of degraded PLLA/PVPh blend was finer than that of PLLA. Young's modulus of PLLA/PVPh blend increased with increasing PVPh content. Yield stress of PLLA/PVPh blends whose …
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