作者
MT Cidade, Catarina R Leal, MH Godinho, AF Martins, P Navard
发表日期
1995/3/1
期刊
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
卷号
261
期号
1
页码范围
617-625
出版商
Taylor & Francis Group
简介
Experimental data for the rheological behavior of two thermotropic liquid crystalline (LC) samples of acetoxypropylcellulose (APC) with different molecular weights, at 120°C, and in shear rates between 0.01 and 10s −1, are presented and analyzed in the framework of the continuum theory for LC polymers recently proposed by Martins1. The viscosity η(γ.)shows a strong shear thinning in the range of shear rates γ. studied, with an hesitation at shear rates of about 0.1-0.2 s−1, depending on the molecular weight, and the first normal stress difference Nl(γ.) shows only positive values, increasing with shear rate γ., with an hesitation at shear rates of an order of magnitude higher, i.e. about 1-2 s−l, also depending on the molecular weight. The hesitation points of the flow functions are displaced towards lower values of the shear rate, with increasing molecular weight. For small and intermediate γ. the shear …
引用总数
199719981999200020012002200320042005200620072008200920102011201220132014201520162017201820192020202120222023213111111221
学术搜索中的文章
MT Cidade, CR Leal, MH Godinho, AF Martins… - Molecular Crystals and Liquid Crystals Science and …, 1995