作者
Jie Chen, Hao Yu, Jingcun Fan, Fengchao Wang, Detang Lu, He Liu, Hengan Wu
发表日期
2017/4/1
期刊
AIP advances
卷号
7
期号
4
出版商
AIP Publishing
简介
Understanding the flow characteristics of shale gas especially in nanopores is extremely important for the exploitation. Here, we perform molecular dynamics (MD) simulations to investigate the hydrodynamics of methane in nanometre-sized slit pores. Using equilibrium molecular dynamics (EMD), the static properties including density distribution and self-diffusion coefficient of the confined methane are firstly analyzed. For a 6 nm slit pore, it is found that methane molecules in the adsorbed layer diffuse more slowly than those in the bulk. Using nonequilibrium molecular dynamics (NEMD), the pressure-driven flow behavior of methane in nanopores is investigated. The results show that velocity profiles manifest an obvious dependence on the pore width and they translate from parabolic flow to plug flow when the width is decreased. In relatively large pores (6–10 nm), the parabolic flow can be described by the Navier …
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