作者
Daniel NT Hay, Juan A Adams, Jason Carpenter, Stephanie L DeVries, John Domyancich, Bruce Dumser, Shawn Goldsmith, Melissa A Kruse, Angela Leone, Farid Moussavi-Harami, Jennifer A O’Brien, Jennifer R Pfaffly, Michael Sylves, Parisa Taravati, Jacob L Thomas, Breck Tiernan, Louis Messerle
发表日期
2004/2/20
期刊
Inorganica chimica acta
卷号
357
期号
3
页码范围
644-648
出版商
Elsevier
简介
Reduction of MoCl5 with Bi in a sealed borosilicate ampule at 350 °C, followed by sublimation of by-product BiCl3 and addition of aqueous hydrochloric acid, yielded chloromolybdic acid, (H3O)2Mo6(μ3-Cl)8Cl6·6H2O, in 80% yield (unoptimized) after double recrystallization. Chloromolybdic acid was thermolyzed to Mo6Cl12 in 95% yield.
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DNT Hay, JA Adams, J Carpenter, SL DeVries… - Inorganica chimica acta, 2004