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In recent years, rare-earth-doped nanophosphors have attracted great attention in the field of luminescent materials for advanced solid-state lighting and high-resolution display applications. However, the low efficiency of concurrent red phosphors creates a major bottleneck for easy commercialization of these devices. In this work, intense red-light-emitting K⁺-codoped BaAl₂O₄:Eu³⁺ nanophosphors having an average crystallite size of 54 nm were synthesized via a modified sol–gel method. The derived nanophosphors exhibit strong red emission produced by the ⁵D₀ → ⁷F_J (J = 0, 1, 2, 3, 4) transitions of Eu³⁺ upon UV and low-voltage electron beam excitation. Comparative photoluminescence (PL) analysis is executed for Eu³⁺-activated and K⁺-coactivated BaAl₂O₄:Eu³⁺ nanophosphors, demonstrating remarkable enhancement in PL intensity as well as thermal stability due to K⁺ codoping. The origin of this PL …