作者
Youngsu Cha, Filippo Cellini, Maurizio Porfiri
发表日期
2013/12
期刊
Physical Review E
卷号
88
期号
6
页码范围
062603
出版商
American Physical Society
简介
Ionic polymer metal composites (IPMCs) are a class of soft electroactive materials that are recently finding extensive application as mechanical sensors and energy harvesters in liquids. In their most fundamental form, IPMCs are composed of a hydrated ionomeric membrane that is sandwiched between two electrochemically deposited metal electrodes. Ionomer swelling, counterion diffusion, and the formation of electric double layers are some of the physical phenomena underpinning energy transduction in IPMCs; however, a thorough understanding of the relative influence of such phenomena is yet to be established. Here, we propose a physics-based modeling framework, based on the Poisson-Nernst-Planck system, to describe IPMC chemoelectrical response to an imposed time-varying flexural deformation. We utilize the method of matched asymptotic expansions to compute a closed-form solution for the …
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