作者
Randall H Pursley, John Kakareka, Ghadi Salem, Nallathamby Devasahayam, Sankaran Subramanian, Rolf G Tschudin, Murali C Krishna, Thomas J Pohida
发表日期
2003/5/1
期刊
Journal of magnetic resonance
卷号
162
期号
1
页码范围
35-45
出版商
Academic Press
简介
The application of correlation spectroscopy employing stochastic excitation and the Hadamard transform to time-domain Fourier transform electron paramagnetic resonance (FT-EPR) spectroscopy in the radiofrequency (RF) band is described. An existing, time-domain FT-EPR spectrometer system with a Larmor frequency (Lf) of 300MHz was used to develop this technique by incorporating a pseudo-random pulse sequence generator to output the maximum length binary sequence (MLBS, 10- and 11-bit). Software developed to control the EPR system setup, acquire the signals, and post process the data, is outlined. The software incorporates the Hadamard transform algorithm to perform the required cross-correlation of the acquired signal and the MLBS after stochastic excitation. To accommodate the EPR signals, bandwidth extension was accomplished by sampling at a rate many times faster than the RF pulse …
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