查看文章

Decamethylcyclopentasiloxane (D₅) is a cyclic volatile methyl siloxane (cVMS) that is widely used in consumer products and commonly observed in urban air. This study quantifies the ambient mixing ratios of D₅ from ground sites in two North American cities (Boulder, CO, USA, and Toronto, ON, CA). From these data, we estimate the diurnal emission profile of D₅ in Boulder, CO. Ambient mixing ratios were consistent with those measured at other urban locations; however, the diurnal pattern exhibited similarities with those of traffic-related compounds such as benzene. Mobile measurements and vehicle experiments demonstrate that emissions of D₅ from personal care products are coincident in time and place with emissions of benzene from motor vehicles. During peak commuter times, the D₅/benzene ratio (w/w) is in excess of 0.3, suggesting that the mass emission rate of D₅ from personal care product usage is …