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Plinian and Ignimbrite deposits represent explosive activity (ca. 17–19 cal ka) within the predominantly effusive and mildly explosive (Strombolian) volcanic history of Mount Etna (Italy). Proximal glasses from the Biancavilla Ignimbrites and Unit D Plinian fall deposits are characterised. Fall deposits recorded at Acireale (D1b and D2b) and Giarre (D1a and D2a) are geochemically distinct confirming they relate to different eruptions. The Acireale Plinian fall (D1b and D2b) deposits compositionally overlap with the Biancavilla Ignimbrite deposits. These explosive eruptions from Etna are considered responsible for widespread ash dispersals throughout the central Mediterranean region, producing the marker tephra layers (Y-1/Et-1) recorded in marine and lacustrine sedimentary archives. Stratigraphically these distal tephras occur at or close to the onset of the last deglaciation (Termination 1) within their respective …