作者
Ze-Min Zhang, Lu-Yi Pan, Wei-Quan Lin, Ji-Dong Leng, Fu-Sheng Guo, Yan-Cong Chen, Jun-Liang Liu, Ming-Liang Tong
发表日期
2013
期刊
Chemical Communications
卷号
49
期号
73
页码范围
8081-8083
出版商
Royal Society of Chemistry
简介
Two unprecedented wheel-shaped nanoscale clusters {CoII16LnIII24} (Ln = Dy and Gd), with a diameter and a thickness of 3.0 nm and 2.0 nm, respectively, were obtained from the self-assembly of Co(NO3)2, Ln(NO3)3 and a pyridyl-functionalized β-diketone ligand. Notably, the gadolinium species exhibited a relatively large magnetocaloric effect.
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