作者
Jeremiah J Scepaniak, Ashley M Wright, Richard A Lewis, Guang Wu, Trevor W Hayton
发表日期
2012/11/28
期刊
Journal of the American Chemical Society
卷号
134
期号
47
页码范围
19350-19353
出版商
American Chemical Society
简介
Addition of 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO) to MCl3 (M = Fe, Al) results in the formation of MCl3(η1-TEMPO) [M = Fe (1), Al (2)]. Both 1 and 2 oxidize alcohols to generate ketones or aldehydes along with the reduced complexes MCl3(η1-TEMPOH) [M = Fe (3), Al (4)]. Complexes 1–4 were fully characterized, including analysis by X-ray crystallography. Additionally, control experiments indicated that neither MCl3 (M = Al, Fe) nor TEMPO are capable of effecting the oxidation of alcohols independently.
学术搜索中的文章
JJ Scepaniak, AM Wright, RA Lewis, G Wu, TW Hayton - Journal of the American Chemical Society, 2012