作者
Leian Bartolome, Muhammad Imran, Kyoung G Lee, Arvin Sangalang, Jeong Keun Ahn
发表日期
2014
期刊
Green Chemistry
卷号
16
期号
1
页码范围
279-286
出版商
Royal Society of Chemistry
简介
There have been numerous studies to develop catalysts for the chemical recycling of poly(ethylene terephthalate) (PET) via glycolysis. However, in the field of PET glycolysis, only a few have attempted to recover and reuse the catalysts. This research utilized easily recoverable superparamagnetic γ-Fe2O3 nanoparticles as a reusable catalyst for PET glycolysis. γ-Fe2O3 nanoparticles were produced by calcining Fe3O4 nanoparticles prepared by the co-precipitation method. The produced γ-Fe2O3 nanoparticles had an average size of 10.5 ± 1.4 nm, and a very high surface area reaching 147 m2 g−1. Its superparamagnetic property was also confirmed. Glycolysis reactions were carried out, and the γ-Fe2O3 catalysts were recovered after the reactions by simple magnetic decantation. The use of magnetic iron oxide allowed the easy recovery of the catalyst from the glycolysis products. At 300 °C and a 0.05 catalyst …
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