作者
Muhammad R Azhar, Hussein R Abid, Vijay Periasamy, Hongqi Sun, Moses O Tade, Shaobin Wang
发表日期
2017/8/15
期刊
Journal of colloid and interface science
卷号
500
页码范围
88-95
出版商
Academic Press
简介
Adsorptive removal of a toxic sulfonamide antibiotic, sulfachloropyradazine (SCP), from aqueous solution was studied on several metal organic frameworks, UiO-66 and ZIF-67, for the first time. UiO-66 exhibited a much higher adsorption capacity than ZIF-67, fast kinetics, and easy regeneration for reuse, demonstrating as a promising adsorbent in wastewater treatment processes. The batch adsorption shows an adsorption capacity of SCP at 417 mg/g on UiO-66. The kinetic adsorption of SCP on UiO-66 reached equilibrium just in 10 min and the kinetics fits accurately with a pseudo 2nd order model. A plausible mechanism was proposed based on pH effect, pKa value of the adsorbate and Zeta potential of UiO-66. The high adsorption is mainly contributed to hydrophobicity and π-π interactions along with electrostatic interactions. Thermodynamic studies show the spontaneous adsorption and exothermic process …
引用总数
20172018201920202021202220232024125254429344027
学术搜索中的文章
MR Azhar, HR Abid, V Periasamy, H Sun, MO Tade… - Journal of colloid and interface science, 2017