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In this study, glucose as a model substance for cellulose is pyrolyzed in supercritical water. The experiments are conducted in a continuously operated tubular reactor. From the usage of model substances, key information on the degradation pathway of biomass in supercritical water can be obtained. With this knowledge, it is tried to optimize a new method for gasification of wet biomass considering high yields of hydrogen and methane and also the suppressing of tar and char formation. The gaseous products mainly contain hydrogen, carbon dioxide, methane and a small amount of carbon monoxide. The effect of experimental conditions, such as pressure, temperature and reaction time, on the degradation of glucose is investigated in the experiments. The qualitative and quantitative composition of the gas and liquid phases formed are determined. The results show that only the amount of phenols increases with …