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As a next‐generation photovoltaic device, perovskite solar cells are rapidly emerging. Nevertheless, both solution and device stability pose challenges for commercialization due to chemical degradation caused by internal and external factors. Especially, the decomposition of iodoplumbate in a perovskite solution hinders the long‐term use of perovskite solutions. Moreover, the synthesis of stable perovskites at low temperature is important for stable devices and wide applications (flexible devices and high reproducibility). Herein, the critical composition of perovskite is found to obtain high stabilities of both iodoplumbate and perovskite crystals by utilizing CsPbBr₃ and FAPbI₃, exhibiting high device performance and long‐term solution storage. The novel composition of CsPbBr₃‐alloyed FAPbI₃ not only crystallizes under annealing‐free conditions but also demonstrates excellent iodoplumbate stability for 100 days …