作者
JL Vega, R Guantes, Salvador Miret-Artés
发表日期
2002
期刊
Physical Chemistry Chemical Physics
卷号
4
期号
20
页码范围
4985-4991
出版商
Royal Society of Chemistry
简介
Calculations of noise-assisted jump rates and diffusion coefficients for diffusion of atoms adsorbed on a metal surface are presented and discussed, in the whole range of the damping strength, and with a direct numerical integration of the Langevin equation, by two different procedures: a mean first passage time calculation and by counting jumps with a given energy criterion. The results are compared to the analytical ones by using the extension of the Kramers model by Mel'nikov and Meshkov. The role of the adiabatic potential coupling in the jump rates, jump distributions and diffusion coefficients is analysed and results are finally compared to previous experimental findings for the Na/Cu(001) system.
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