作者
C Bailey, Katalin Fodor-Csorba, James T Gleeson, Samuel N Sprunt, Antal Jákli
发表日期
2009
期刊
Soft Matter
卷号
5
期号
19
页码范围
3618-3622
出版商
Royal Society of Chemistry
简介
We show that bent-core liquid crystalline materials exhibit non-Newtonian flow in their optically isotropic liquid phase. We conjecture that this behavior is due to the existence of nanostructured, fluctuating clusters composed of a few smectic-like layers. Shear alignment of these clusters explains the shear thinning observed in bent-core liquid crystals having either a nematic phase or non-modulated smectic phase. By contrast, smectogens having a modulated smectic phase do not shear thin at low shear rates, but even show a slight shear thickening which may be due to entanglements of wormlike and/or helical clusters.
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C Bailey, K Fodor-Csorba, JT Gleeson, SN Sprunt… - Soft Matter, 2009