作者
Zhaofeng Wang, Li Li, Yong Huang
发表日期
2014/9/3
期刊
Journal of the American Chemical Society
卷号
136
期号
35
页码范围
12233-12236
出版商
American Chemical Society
简介
We describe a direct synthesis of various ynones from readily available aldehydes and hypervalent alkynyl iodides. In this method, a gold catalyst and a secondary amine work synergistically to produce the trisubstituted allenyl aldehyde, which can be converted to the desired ynone through an in situ C–C bond oxidative cleavage using molecular oxygen.
学术搜索中的文章
Z Wang, L Li, Y Huang - Journal of the American Chemical Society, 2014